dc.contributor.author | Nadeem, Said | |
dc.contributor.author | Shah, Muhammad R. | |
dc.contributor.author | Ali, Qamar | |
dc.contributor.author | Hussain, Zahid | |
dc.date.accessioned | 2020-11-20T15:07:34Z | |
dc.date.available | 2020-11-20T15:07:34Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1570-1786 | |
dc.identifier.issn | 1875-6255 | |
dc.identifier.uri | https://doi.org/10.2174/157017861207150708113303 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12809/3254 | |
dc.description | Nadeem, Said/0000-0001-5025-9326; | en_US |
dc.description | WOS: 000357692800009 | en_US |
dc.description.abstract | A rigid shape-persistent fluorescent macrocycle PhenMac was synthesized using Sonogashira coupling reaction and TIPS-decoupling in a single pot. 2,9-dichloro-1,10-phenanthroline was reacted with TIPS-protected diyne 2 in the presence of Pd(PPh3)(2)Cl-2, CuI and TBAF at 100 degrees C. PhenMac was obtained as yellow fluorescent compound; characterized by NMR, ESI, MALDI-TOF, CHN, IR and UV-visible spectroscopy. In chloroform, PhenMac showed lambda(ex-max) at 331 nm while lambda(em-max) was observed at 407 nm. Under UV light, PhenMac showed more fluorescence in CHCl3, ethanol, and DMF while the fluorescence was quenched in triethylamine. PhenMac will be used in various applications of [poly]catenanes, supramolecular chemistry and nanotechnology. | en_US |
dc.description.sponsorship | Higher Education Commission of PakistanHigher Education Commission of Pakistan | en_US |
dc.description.sponsorship | We are thankful to the Higher Education Commission of Pakistan for financial support International Center for Chemical and Biological Sciences, HEJ Research Institute of Chemistry, University of Karachi, Pakistan for all facilities used during the project. | en_US |
dc.item-language.iso | eng | en_US |
dc.publisher | Bentham Science Publ Ltd | en_US |
dc.item-rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Shape-Persistent Macrocycles | en_US |
dc.subject | Sonogashira Coupling of Aryl Chlorides | en_US |
dc.subject | 1,10-Phenanthroline | en_US |
dc.subject | Fluorescent Macrocycles | en_US |
dc.title | One Pot Synthesis of 1,10-Phenanthroline-based Shape-Persistent Flouroscent Macrocycle Using Sonogashira Coupling | en_US |
dc.item-type | article | en_US |
dc.contributor.department | MÜ | en_US |
dc.contributor.departmentTemp | [Nadeem, Said] Mugla Sitki Kocman Univ, Fac Sci, Dept Chem, TR-48121 Kotekli, Mugla, Turkey -- [Nadeem, Said] Mugla Univ, Koyceyiz Vocat Sch, Dept Med & Aromat Plants, TR-48000 Mugla, Turkey -- [Shah, Muhammad R.; Ali, Qamar] Univ Karachi, Int Ctr Chem & Biol Sci, HEJ Res Inst Chem, Karachi 75270, Pakistan -- [Hussain, Zahid] Univ Karachi, Dept Chem, Karachi 75270, Pakistan | en_US |
dc.identifier.doi | 10.2174/157017861207150708113303 | |
dc.identifier.volume | 12 | en_US |
dc.identifier.issue | 7 | en_US |
dc.identifier.startpage | 504 | en_US |
dc.identifier.endpage | 510 | en_US |
dc.relation.journal | Letters in Organic Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |