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dc.contributor.authorNadeem, Said
dc.contributor.authorShah, Muhammad R.
dc.contributor.authorAli, Qamar
dc.contributor.authorHussain, Zahid
dc.date.accessioned2020-11-20T15:07:34Z
dc.date.available2020-11-20T15:07:34Z
dc.date.issued2015
dc.identifier.issn1570-1786
dc.identifier.issn1875-6255
dc.identifier.urihttps://doi.org/10.2174/157017861207150708113303
dc.identifier.urihttps://hdl.handle.net/20.500.12809/3254
dc.descriptionNadeem, Said/0000-0001-5025-9326;en_US
dc.descriptionWOS: 000357692800009en_US
dc.description.abstractA rigid shape-persistent fluorescent macrocycle PhenMac was synthesized using Sonogashira coupling reaction and TIPS-decoupling in a single pot. 2,9-dichloro-1,10-phenanthroline was reacted with TIPS-protected diyne 2 in the presence of Pd(PPh3)(2)Cl-2, CuI and TBAF at 100 degrees C. PhenMac was obtained as yellow fluorescent compound; characterized by NMR, ESI, MALDI-TOF, CHN, IR and UV-visible spectroscopy. In chloroform, PhenMac showed lambda(ex-max) at 331 nm while lambda(em-max) was observed at 407 nm. Under UV light, PhenMac showed more fluorescence in CHCl3, ethanol, and DMF while the fluorescence was quenched in triethylamine. PhenMac will be used in various applications of [poly]catenanes, supramolecular chemistry and nanotechnology.en_US
dc.description.sponsorshipHigher Education Commission of PakistanHigher Education Commission of Pakistanen_US
dc.description.sponsorshipWe are thankful to the Higher Education Commission of Pakistan for financial support International Center for Chemical and Biological Sciences, HEJ Research Institute of Chemistry, University of Karachi, Pakistan for all facilities used during the project.en_US
dc.item-language.isoengen_US
dc.publisherBentham Science Publ Ltden_US
dc.item-rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectShape-Persistent Macrocyclesen_US
dc.subjectSonogashira Coupling of Aryl Chloridesen_US
dc.subject1,10-Phenanthrolineen_US
dc.subjectFluorescent Macrocyclesen_US
dc.titleOne Pot Synthesis of 1,10-Phenanthroline-based Shape-Persistent Flouroscent Macrocycle Using Sonogashira Couplingen_US
dc.item-typearticleen_US
dc.contributor.departmenten_US
dc.contributor.departmentTemp[Nadeem, Said] Mugla Sitki Kocman Univ, Fac Sci, Dept Chem, TR-48121 Kotekli, Mugla, Turkey -- [Nadeem, Said] Mugla Univ, Koyceyiz Vocat Sch, Dept Med & Aromat Plants, TR-48000 Mugla, Turkey -- [Shah, Muhammad R.; Ali, Qamar] Univ Karachi, Int Ctr Chem & Biol Sci, HEJ Res Inst Chem, Karachi 75270, Pakistan -- [Hussain, Zahid] Univ Karachi, Dept Chem, Karachi 75270, Pakistanen_US
dc.identifier.doi10.2174/157017861207150708113303
dc.identifier.volume12en_US
dc.identifier.issue7en_US
dc.identifier.startpage504en_US
dc.identifier.endpage510en_US
dc.relation.journalLetters in Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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