Homo- and heteronuclear complexes of a new, vicinal dioxime ligand

Abstract

A new symmetrical vicinal dioxime, N,N'-bis-{4-[[(2-hydroxyphenyl)methylene]hydrazinecarbonyl]phenyl}diaminoglyoxime (LH4), was prepared by reacting anti-dichloroglyoxime with salicylaldehyde 4-aminobenzoylhydrazone. The reaction of ligand with Ni2+ salts gave mono-and homopentanuclear complexes, [Ni(LH3)(2)] and [Ni-5(LH)(2)X-2]. Furthermore, heteropentanuclear complexes of dioxime ligand, [Cu4Ni(LH)(2)X-4], were prepared by the reaction of [Ni(LH3)(2))] with Cu2+ salt and a monodentate ligand (X = SCN-, CN-, or N-3(-)). The structures of both the new symmetrical vicinal dioxime and its complexes were identified by elemental analyses, IR, H-1 NMR, UV-VIS spectra, and magnetic susceptibility. The elemental analyses and spectral data indicate that the hydrazone side of ligand acts as a O,N,O' tridentate and the fourth position is occupied with monodentate anion such as SCN-, CN-, N-3(-).