| dc.contributor.author | Erkarslan, Uğur | |
| dc.contributor.author | Oylumluoğlu, Görkem | |
| dc.contributor.author | Çoban, M. Burak | |
| dc.contributor.author | Özturk, Esra | |
| dc.contributor.author | Kara, Hülya | |
| dc.date.accessioned | 2020-11-20T15:02:32Z | |
| dc.date.available | 2020-11-20T15:02:32Z | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 0020-1693 | |
| dc.identifier.issn | 1873-3255 | |
| dc.identifier.uri | https://doi.org/10.1016/j.ica.2016.02.010 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12809/2528 | |
| dc.description | WOS: 000372747600008 | en_US |
| dc.description.abstract | A trinuclear cyanide-bridged Mn-III-Fe-III compound, [NEt4][Mn(3,5-ClL)(2)(MeOH)](2)Fe(CN)(6)], [3,5-ClLH2 = N, N'-bis(3,5-chlorosalicylidenato)-1,2-diamino propane)], 1, has been characterized by X-ray analyses, magnetic and photoluminescence measurements. The structure assumes a two-dimensional network consisting of Mn-NC-Fe-CN-Mn (Fe1-C19-N4 = 175.9(3)degrees, C19-N4-Mn1 = 145.5 (3)degrees). The magnetic properties of this compound indicate antiferromagnetic coupling between low-spin Fe(III) and high-spin Mn(III) through the cyanide bridges. Furthermore, solid state photoluminescence properties of complex 1 have been investigated at room temperature. (C) 2016 Elsevier B.V. All rights reserved. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-108T431]; Royal Society short visit fellowship | en_US |
| dc.description.sponsorship | The authors are grateful to the Scientific and Technological Research Council of Turkey (TUBITAK) (Grant number TBAG-108T431) for the financial support. Dr. Kara would like to thank TUBITAK for NATO-B1 and the Royal Society short visit fellowship for financial support and Prof. A. Guy Orpen (School of Chemistry, University of Bristol, UK) for his hospitality. The authors are also very grateful to Dr. Andrea Caneschi and Dr. Lorenzo Sorace (Department of Chemistry, University of Florence) for the SQUID measurements. | en_US |
| dc.item-language.iso | eng | en_US |
| dc.publisher | Elsevier Science Sa | en_US |
| dc.item-rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Magnetism | en_US |
| dc.subject | Photoluminescence | en_US |
| dc.subject | X-Ray Analyses | en_US |
| dc.subject | Cyano-Bridged | en_US |
| dc.subject | Mn-III-Fe-III Compound | en_US |
| dc.title | Cyanide-bridged trinuclear Mn-III-Fe-III assembly: Crystal structure, magnetic and photoluminescence behavior | en_US |
| dc.item-type | article | en_US |
| dc.contributor.department | MÜ, Fen Fakültesi, Fizik Bölümü | en_US |
| dc.contributor.institutionauthor | Erkarslan, Uğur | |
| dc.identifier.doi | 10.1016/j.ica.2016.02.010 | |
| dc.identifier.volume | 445 | en_US |
| dc.identifier.startpage | 57 | en_US |
| dc.identifier.endpage | 61 | en_US |
| dc.relation.journal | Inorganica Chimica Acta | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
