| dc.contributor.author | Yahşi, Yasemin | |
| dc.contributor.author | Güngör, Elif | |
| dc.contributor.author | Çoban, M. Burak | |
| dc.contributor.author | Kara, Hülya | |
| dc.date.accessioned | 2020-11-20T15:03:08Z | |
| dc.date.available | 2020-11-20T15:03:08Z | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1542-1406 | |
| dc.identifier.issn | 1563-5287 | |
| dc.identifier.uri | https://doi.org/10.1080/15421406.2016.1177918 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12809/2669 | |
| dc.description | 0000-0002-2032-8930 | en_US |
| dc.description | WOS: 000388605400008 | en_US |
| dc.description.abstract | A new linear trinuclear Mn-III-Mn-II-Mn-III complex 1 has been synthesized and characterized by elemental, spectral, X-ray and magnetic analysis. X-ray diffraction studies show that the central Mn-II ion is located at a crystallographic inversion center and is triply bridged to the terminal Mn-III ions through one methoxide, one syn-syn carboxylate and one hydroxyl oxygen bridges with the short Mn-III center dot center dot center dot Mn-II distance that is 3.047 angstrom. The intermolecular C-H center dot center dot center dot O, C-H center dot center dot center dot pi and ring-metal interactions are observed in the hydrogen-bonded assembly of 1. Magnetic studies reveal that themixed-valence complex 1 has S = 3/2 ground state with antiferromagnetic exchange interactions between Mn-II and Mn-III ions. | en_US |
| dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-108T431]; Balikesir UniversityBalikesir University [2015/50]; Nato-B1-TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) | en_US |
| dc.description.sponsorship | The authors are grateful to the Scientific and Technical Research Council of Turkey (TUBITAK, Grants No. TBAG-108T431) and Balikesir University (Project No. 2015/50) for the financial supports. Dr. Kara also thanks to the Nato-B1-TUBITAK for funding and to Prof. Guy Orpen (School of Chemistry, University of Bristol, UK) for his hospitality. | en_US |
| dc.item-language.iso | eng | en_US |
| dc.publisher | Taylor & Francis Ltd | en_US |
| dc.item-rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Schiff Base | en_US |
| dc.subject | Mixed-Valance Mn Complex | en_US |
| dc.subject | X-Ray Crystal Structure | en_US |
| dc.subject | Magnetic Properties | en_US |
| dc.title | Linear trinuclear mixed valance Mn-III-Mn-II-Mn-III complex: Synthesis, crystal structure and characterization | en_US |
| dc.item-type | article | en_US |
| dc.contributor.department | MÜ, Fen Fakültesi, Fizik Bölümü | en_US |
| dc.contributor.institutionauthor | Kara, Hülya | |
| dc.identifier.doi | 10.1080/15421406.2016.1177918 | |
| dc.identifier.volume | 637 | en_US |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.startpage | 67 | en_US |
| dc.identifier.endpage | 75 | en_US |
| dc.relation.journal | Molecular Crystals and Liquid Crystals | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
