| dc.contributor.author | Gungor, E. | |
| dc.contributor.author | Kara, H. | |
| dc.date.accessioned | 2020-11-20T15:04:08Z | |
| dc.date.available | 2020-11-20T15:04:08Z | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 0022-4766 | |
| dc.identifier.issn | 1573-8779 | |
| dc.identifier.uri | https://doi.org/10.1134/S0022476615080296 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12809/2838 | |
| dc.description | KARA, Hulya/0000-0002-2032-8930 | en_US |
| dc.description | WOS: 000369060800029 | en_US |
| dc.description.abstract | A new tetranuclear complex [Cu-4(L)(4)] (1) (H2L = N-(2-hydroxyethyl)-3-metoxysalicylaldimine) has been synthesized and characterized by crystal structure analysis and magnetic susceptibility. Single-crystal X-ray diffraction studies reveal that complex 1 contains three independent Cu4O4 open-cubane cores of 4+2 type (four short and two long Cu center dot center dot center dot Cu distances), where the copper(II) centers are linked by alkoxo-bridges. Each copper(II) ion have a distorted square-pyramidal geometry. Variable-temperature magnetic susceptibility measurements on the tetranuclear complex 1 in the range 2-300 K indicate dominant antiferromagnetic coupling (J =-108.46) between copper(II) centers. | en_US |
| dc.description.sponsorship | TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-108T431]; Balikesir UniversityBalikesir University [BAP-2012/122]; Nato-B1-TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK); Royal SocietyRoyal Society of London | en_US |
| dc.description.sponsorship | The authors are grateful to TUBITAK (Grants No.: TBAG-108T431) and the Research Funds of Balikesir University (BAP-2012/122) for the financial support. Dr. Kara also thanks the Nato-B1-TUBITAK and the Royal Society short visit fellowship for financial support and Prof. Guy Orpen (School of Chemistry, University of Bristol, UK) for his hospitality. The authors are also very grateful to Dr. Mairi F. Haddow (The School of Chemistry, University of Bristol) for the X-ray measurement, and Dr. Lorenzo Sorace and Dr. Andrea Caneschi (Department of Chemistry, University of Florence) for the SQUID measurements. | en_US |
| dc.item-language.iso | eng | en_US |
| dc.publisher | Pleiades Publishing Inc | en_US |
| dc.item-rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Schiff Base | en_US |
| dc.subject | Tetranuclear Copper(II) Complex | en_US |
| dc.subject | Antiferromagnetic Interaction | en_US |
| dc.title | A new tetranuclear distorted open-cubane copper(II) Schiff base complex: Structural, spectral and magnetic characterizations | en_US |
| dc.item-type | article | en_US |
| dc.contributor.department | MÜ | en_US |
| dc.contributor.departmentTemp | [Gungor, E.; Kara, H.] Balikesir Univ, Fac Sci & Art, Dept Phys, Balikesir, Turkey -- [Kara, H.] Mugla Sitki Kocman Univ, Dept Phys, Fac Sci, Mugla, Turkey | en_US |
| dc.identifier.doi | 10.1134/S0022476615080296 | |
| dc.identifier.volume | 56 | en_US |
| dc.identifier.issue | 8 | en_US |
| dc.identifier.startpage | 1646 | en_US |
| dc.identifier.endpage | 1652 | en_US |
| dc.relation.journal | Journal of Structural Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
