dc.contributor.author | Xue, Chenming | |
dc.contributor.author | Birel, Özgül | |
dc.contributor.author | Xue, Yuhua | |
dc.contributor.author | Dai, Liming | |
dc.contributor.author | Urbas, Augustine | |
dc.contributor.author | Li, Quan | |
dc.date.accessioned | 2020-11-20T16:19:53Z | |
dc.date.available | 2020-11-20T16:19:53Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1932-7447 | |
dc.identifier.issn | 1932-7455 | |
dc.identifier.uri | https://doi.org/10.1021/jp400788h | |
dc.identifier.uri | https://hdl.handle.net/20.500.12809/3819 | |
dc.description | WOS: 000317317600031 | en_US |
dc.description.abstract | Hydrophilic mercaptosuccinic acid (MSA) monolayer-protected gold nanorods (GNRs) were synthesized. The resulting GNRs encapsulated with biocompatible MSA molecules via covalent Au-S linkages were found to be able to self-aggregate through intermolecular hydrogen bonding. Interestingly, when the hybrid GNRs (MSA-GNR) were mixed with the hydrophilic fluorescent perylene diimide (PDI) molecules and carboxylic acid modified single-wall carbon nanotubes (CNT-COOH), respectively, their aggregation behaviors were pH- and temperature-dependent, which were investigated by UV-vis, fluorescence spectra, and TEM images. The aggregates of MSA-GNR with functional PDI and CNT-COOH were able to combine the properties of each component through noncovalent interactions, providing insight into developing new multifunctional metal nanocomposites with properties tailored for their practical application. | en_US |
dc.description.sponsorship | Air Force Office of Scientific ResearchUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR) [AFOSR FA9550-09-1-0254]; AFOSR-MURIUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR)MURI [FA9550-12-1-0037]; TUBITAK from TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [2219] | en_US |
dc.description.sponsorship | This work was supported by the Air Force Office of Scientific Research (Grant AFOSR FA9550-09-1-0254). Support from AFOSR-MURI (Grant FA9550-12-1-0037) and TUBITAK (Grant 2219) from Turkey is also acknowledged. The TEM data were obtained with assistance from Min Gao at the (cryo) TEM facility at the Liquid Crystal Institute, Kent State University, OH, supported by the Ohio Research Scholars Program Research Cluster on Surfaces in Advanced Materials. | en_US |
dc.item-language.iso | eng | en_US |
dc.publisher | Amer Chemical Soc | en_US |
dc.item-rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | pH and Temperature Modulated Aggregation of Hydrophilic Gold Nanorods with Perylene Dyes and Carbon Nanotubes | en_US |
dc.item-type | article | en_US |
dc.contributor.department | MÜ, Fen Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Birel, Özgül | |
dc.identifier.doi | 10.1021/jp400788h | |
dc.identifier.volume | 117 | en_US |
dc.identifier.issue | 13 | en_US |
dc.identifier.startpage | 6752 | en_US |
dc.identifier.endpage | 6758 | en_US |
dc.relation.journal | Journal of Physical Chemistry C | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |